ii. B,Hg(五硼烷nido-pentaborane VO:价轨道数 巢式五硼烷 VE:价电子数 ·VO=5x4(B)+9(H)=29 ·VE=5x3(B)+9x1(H)=24e 1)5 B-H o-bonds;(10e) 2)4 BHB 3c-2e bonds;(8e) 3)a B5 5c-6e bond.(6e) 0 Each peripheral B atom contributes one sp3-HO and one electron. ·The central B atom contributes three sp3-HO's and 2e. A nido structure
iii. B5H9（五硼烷 nido-pentaborane） B H H B H H B H B H B H H H A nido structure VO：价轨道数 巣式五硼烷 VE：价电子数
Chemical bonds in Boranes (a)Single bond B-H B-B H (b)3center-2electron bonds B B (c)Other polycenter-polyelectron bond B
B-H B-B (c) Other polycenter-polyelectron bond (b) 3center-2electron bonds (a) Single bond Chemical bonds in Boranes
There are many boranes and carboranes,how to determine the geometric and electronic structure for more complicated boranes? Structure of Boranes(n equals to number of B-H bonds) B4H10 B.Hg B6H10 BaH12 B10H14
There are many boranes and carboranes, how to determine the geometric and electronic structure for more complicated boranes ? Structure of Boranes (n equals to number of B-H bonds) B 4 H10 B 5 H 9 B 6 H10 B 8 H12 B10 H14
6.1.2 For B H+m's open structure(including nido and arachno) In the mid 1950s,Lipscomb proposed the styx method to predict the topological structures of boranes BHn+m with open structures.Lipscomb was awarded Nobel prize "for his studies on the structure of boranes"in 1976.he passed away on Apr. 14,2011. William Lipscomb(American) Nobel speech: Boranes and their chemical bonding uilliam
6.1.2 For BnHn+m’s open structure (including nido and arachno) In the mid 1950s, Lipscomb proposed the styx method to predict the topological structures of boranes BnHn+m with open structures. Lipscomb was awarded Nobel prize “for his studies on the structure of boranes” in 1976. he passed away on Apr. 14, 2011. William Lipscomb（American) Nobel speech: Boranes and their chemical bonding
The topological analysis for BHn+m's with open structure n:the number of B atoms,also the minimal number of B-H bonds m:the number of extra H atomes 硼烷结构的拓扑分析法styx method B:Ho B
B H H B H H B H B H B H H H B B H B B B B B H B B B B H H B B s t y x B5H9 硼烷结构的拓扑分析法 styx method The topological analysis for BnHn+m’s with open structure n: the number of B atoms, also the minimal number of B-H bonds m:the number of extra H atomes