Examples of Nomenclature CH3 OH CH3一CH-CH2OH CH3-CH-CH2CH3 3 21 12 34 2-methyl-1-propanol 2-butanol 2-methylpropan-1-ol butan-2-ol CH3 1 2-methyl-2-propanol 2-methylpropan-2-ol CH3 Chapter 10 6
Chapter 10 6 Examples of Nomenclature 2-methyl-1-propanol 2-methylpropan-1-ol 2-methyl-2-propanol 2-methylpropan-2-ol 2-butanol butan-2-ol CH3 C CH3 CH3 OH CH3 CH CH3 CH2OH CH3 CH OH CH2CH3 3 2 1 1 2 3 4 2 1
Alkenols (Enols) Hydroxyl group takes precedence.Assign the carbon with the-OH the lowest number. End the name in-o/,but also specify that there is a double bond by using the ending -ene before-ol OH CH2-CHCH2CHCH3 54321 4-penten-2-ol pent-4-ene-2-ol Chapter 10 7
Chapter 10 7 Alkenols (Enols) • Hydroxyl group takes precedence. Assign the carbon with the —OH the lowest number. • End the name in –ol, but also specify that there is a double bond by using the ending –ene before -ol 4-penten-2-ol pent-4-ene-2-ol CH2 CHCH2CHCH3 OH 5 4 3 2 1
Naming Priority Highest ranking 1.Acids 2.Esters 3.Aldehydes 4.Ketones 5.Alcohols 6.Amines 7. Alkenes 8.Alkynes 9.Alkanes 10.Ethers Lowest ranking 11.Halides Chapter 10 8
Chapter 10 8 Naming Priority 1. Acids 2. Esters 3. Aldehydes 4. Ketones 5. Alcohols 6. Amines 7. Alkenes 8. Alkynes 9. Alkanes 10. Ethers 11. Halides Highest ranking Lowest ranking
Hydroxy Substituent When-OH is part of a higher priority class of compound,it is named as hydroxy. carboxylic acid OH CH2CH2CH2COOH 4321 4-hydroxybutanoic acid also known as y-hydroxybutyric acid (GHB) Chapter 10 9
Chapter 10 9 Hydroxy Substituent • When —OH is part of a higher priority class of compound, it is named as hydroxy. 4-hydroxybutanoic acid also known as g-hydroxybutyric acid (GHB) CH2CH2CH2COOH OH carboxylic acid 4 3 2 1
Common Names Alcohol can be named as alkyl alcohol. Useful only for small alkyl groups. CH3 QH CH3-CH-CH2OH CH3-CH-CH2CH3 isobutyl alcohol sec-butyl alcohol Chapter 10 10
Chapter 10 10 Common Names • Alcohol can be named as alkyl alcohol. • Useful only for small alkyl groups. isobutyl alcohol sec-butyl alcohol CH3 CH CH3 CH2OH CH3 CH OH CH2CH3