Organic Chemistry,6th Edition L.G.Wade,Jr. Chapter 26 Lipids CH2-0一 0 CH 一0 CH2一O tristearin,mp 72C O- CH2一O一 CH一O一 y Junru Wang CH2-O- r07@163.c0m triolein,mp-4C 0球4试 灌率昆
By Junru Wang Email: wangjr07@163.com Chapter 26 Lipids Organic Chemistry, 6th Edition L. G. Wade, Jr
Introduction Classified by solubility,not structure. Can be extracted from cells by nonpolar organic solvents. Complex lipids are easily hydrolyzed. ●Waxes ●Triglycerides Simple lipids are not easily hydrolyzed. ●Steroids ●Prostaglandins ●Terpenes
Introduction ◼Classified by solubility, not structure. ◼Can be extracted from cells by nonpolar organic solvents. ◼Complex lipids are easily hydrolyzed. ⚫Waxes ⚫Triglycerides ◼Simple lipids are not easily hydrolyzed. ⚫Steroids ⚫Prostaglandins ⚫Terpenes
Examples of Lipids Examples of complex lipids Examples of simple lipids CH2-O-C-(CH2)16CH3 H30 HO tristearin,a fat cholesterol,a steroid CH3(CH2)15-O-C-(CH2)14CH3 spermaceti (cetyl palmitate),a wax a-pinene,a terpene Copyright2005 Pearson Prentice Hall,Inc
Examples of Lipids
Waxes Esters of long-chain fatty acids with long-chain alcohols. Spermaceti is found in the head of the sperm whale and is probably used to control buoyancy. Most natural waxes are protective coats for plants'leaves,insects'exoskeletons, mammals'fur,and birds'feathers
Waxes ◼Esters of long-chain fatty acids with long-chain alcohols. ◼Spermaceti is found in the head of the sperm whale and is probably used to control buoyancy. ◼Most natural waxes are protective coats for plants’ leaves, insects’ exoskeletons, mammals’ fur, and birds’ feathers
Triglycerides Fatty acid esters of glycerol. ■Fats Solid at room temperature oMost are derived from mammals ■Oils Liquid at room temperature Most are derived from plants or cold-blooded animals
Triglycerides ◼Fatty acid esters of glycerol. ◼Fats ⚫Solid at room temperature ⚫Most are derived from mammals ◼Oils ⚫Liquid at room temperature ⚫Most are derived from plants or cold-blooded animals