Organic Chemistry,6th Edition L.G.Wade,Jr. Chapter 25 Lipids Jo Blackburn Richland College,Dallas,TX Dallas County Community College District ©2006，Prentice Hall
Chapter 25 Lipids Jo Blackburn Richland College, Dallas, TX Dallas County Community College District © 2006, Prentice Hall Organic Chemistry, 6th Edition L. G. Wade, Jr
Introduction Classified by solubility,not structure. Can be extracted from cells by nonpolar organic solvents. Complex lipids are easily hydrolyzed. >Waxes >Triglycerides 。 Simple lipids are not easily hydrolyzed. >Steroids >Prostaglandins >Terpenes Chapter 25 => 2
Chapter 25 2 Introduction • Classified by solubility, not structure. • Can be extracted from cells by nonpolar organic solvents. • Complex lipids are easily hydrolyzed. ➢Waxes ➢Triglycerides • Simple lipids are not easily hydrolyzed. ➢Steroids ➢Prostaglandins ➢Terpenes =>
Examples of Lipids Examples of complex lipids Examples of simple lipids 0 CH2-O-C-(CH2)16CH3 - H3 d-o8cwa HO tristearin,a fat cholesterol,a steroid CH3(CH2)15-O-C-(CH2)14CH3 spermaceti(cetyl palmitate),a wax a-pinene,a terpene 三> Copyright2005 Pearson Prentice Hall,Inc. 3
Chapter 25 3 Examples of Lipids =>
Waxes Esters of long-chain fatty acids with long-chain alcohols. Spermaceti is found in the head of the sperm whale and is probably used to control buoyancy. Most natural waxes are protective coats for plants'leaves,insects'exoskeletons, mammals'fur,and birds'feathers. 二> Chapter 25
Chapter 25 4 Waxes • Esters of long-chain fatty acids with long-chain alcohols. • Spermaceti is found in the head of the sperm whale and is probably used to control buoyancy. • Most natural waxes are protective coats for plants’ leaves, insects’ exoskeletons, mammals’ fur, and birds’ feathers. =>
Triglycerides Fatty acid esters of glycerol. ·Fats >Solid at room temperature >Most are derived from mammals 。Oils >Liquid at room temperature >Most are derived from plants or cold- blooded animals. => Chapter 25 5
Chapter 25 5 Triglycerides • Fatty acid esters of glycerol. • Fats ➢Solid at room temperature ➢Most are derived from mammals • Oils ➢Liquid at room temperature ➢Most are derived from plants or coldblooded animals. =>