Classify CH3 CH3 CH3 CH3—C-NH2 Br CH3 CH3CH2-N-CH2CH3 CH3 CH3 CH2--N--Cn2H2sBr 新洁尔灭季铵盐阳离子表面活性广 谱杀菌剂/去垢;广泛用于手、皮肤、 粘膜、器械等的消毒。不适用于膀胱镜、 CH3 眼科器械、橡胶及铝制品的消毒。 溴化N一十二烷基一N,N一二甲基苄铵 (或N一十二烷基一N,N一二甲基苄基溴化铵)
Classify N H CH3 C CH3 CH3 NH2 N CH3 CH3 CH3CH2 N CH3 CH2CH3 + Br _ CH2 N CH3 CH3 [ C12H25 ] + Br - 溴化N-十二烷基-N,N-二甲基苄铵 (或N-十二烷基-N,N-二甲基苄基溴化铵) 新洁尔灭 季铵盐阳离子表面活性广 谱杀菌剂/去垢;广泛用于手、皮肤、 粘膜、器械等的消毒。不适用于膀胱镜、 眼科器械、橡胶及铝制品的消毒
Amine as Substituent On a molecule with a higher priority functional group the amine is named as a substituent. OH y B c CH,CHCH2一C00H H-N 3-aminocyclopentene y-aminobutyric acid trans-3-aminocyclohexanol p-aminobenzoic acid (PABA) (cyclopent-2-en-1-amine) (4-aminobutanoic acid) Copyright 2010 Pearson Prentice Hall,Inc. PABA:染料和医药中间体;PABA可帮助减少脱发和消灭白发。它对许多种皮肤病 都有很好的疗效:皮炎、疱疹、红斑狼疮、皮下成淋巴细胞瘤以及硬皮病。作防 晒剂:外敷PABA,同时内服B6,降低中暑和太阳灼伤。能防止和减少皮肤皱纹
Amine as Substituent ◼On a molecule with a higher priority functional group the amine is named as a substituent. PABA: 染料和医药中间体; PABA可帮助减少脱发和消灭白发。它对许多种皮肤病 都有很好的疗效:皮炎、疱疹、红斑狼疮、皮下成淋巴细胞瘤以及硬皮病。 作防 晒剂: 外敷PABA,同时内服B6,降低中暑和太阳灼伤。能防止和减少皮肤皱纹
IUPAC Names Name is based on longest carbon chain. -e of alkane is replaced with -amine. Substituents on nitrogen have N prefix. Br N(CH3)2 NH2CH2CH2CHCHCH3 CH:CHCHCHCH2CH3 3-bromo-1-pentanamine N,N-dimethyl-3-hexanamine
IUPAC Names ◼Name is based on longest carbon chain. ◼-e of alkane is replaced with -amine. ◼Substituents on nitrogen have N- prefix. NH2 CH2 CH2 CHCH2 CH3 Br CH3 CH2 CHCH2 CH2 CH3 N(CH3 ) 2 3-bromo-1-pentanamine N,N-dimethyl-3-hexanamine
Aromatic Amines Amino group is bonded to a benzene ring. Parent compound is called aniline. NH2 N(CH2CH3)2 CH2CH3 CH aniline 2-ethylaniline N.N-diethylaniline 4-methylaniline or o-ethylaniline or p-toluidine Copyright 2010 Pearson Prentice Hall,Inc
Aromatic Amines Amino group is bonded to a benzene ring. Parent compound is called aniline
Heterocyclic Amines The nitrogen is assigned the number 1. H CH3 aziridine pyrrole pyrrolidine 1-methylpyrrolidine imidazole indole (N-methylpyrrolidine) CH3 pyridine 2-methylpyridine piperidine Pyrimidine purine Copyright 2010 Pearson Prentice Hall,Inc
Heterocyclic Amines The nitrogen is assigned the number 1