experiment 口一口 RRKM
RRKM
Model complex reactions reaction contains more than one elementary reactions 1) Opposing reaction对峙反应 2)Parallel reaction 平行反应 3) Consecutive reaction连续反应
Model complex reactions reaction contains more than one elementary reactions 1) Opposing Reaction 2) Parallel Reaction 3) Consecutive Reaction 对峙反应 平行反应 连续反应
Opposing reaction reversible reaction majority of the reactions are reversible, i.e the forward and the backward/ reverse reaction take place simultaneously. aa+bB gG+ hH =k[4[By_k[4By=k[G团 k. [G]HI r=kIGLHI k [A[B]
aA + bB gG + hH k+ k- a b r k [A] [B] + = + g h r k [G] [H] − = − Opposing Reaction reversible reaction majority of the reactions are reversible, i.e., the forward and the backward / reverse reaction take place simultaneously. a b g h k [A] [B] k [G] [H] + = − a b g h A B G H k k [ ] [ ] [ ] [ ] = − + = Kc